Wearing Valentino haute couture, Balfe brought old school glamour as she made her way through the red carpet. The black dress paired with a sheer pink overlay and oversized bow features a mermaid silhouette.

Wiig makes a remarkable entrance in this bold Valentino number, designed with ruffle details and a dramatic train which she wore with evening gloves. 

In pristine-white custom Emporio Armani one-shoulder dress, Best Actress Zellweger looked radiant. Quickly becoming her signature look, she kept everything else minimal and undone. 

Natalie Portman is regal in a black and gold Dior ensemble, featuring a cape, gold embellishments and name embroidery. Her chopped locks and nude lips kept this ensemble looking youthful and fresh.

Another cape number, Larson hit the mark in this sparkly and fully-sequined Elie Saab evening gown. She kept this look modern, by opting for a sleek updo and barely-there make up.

A white rose, a pearl belt, Cruz's vintage frock had all the elements that makes a Chanel gown unmistakable. A classic, old Hollywood look which she paired down with loose straight hair.